100% Blaziken

Already have a level 40 100% Blaziken with Blast Burn, now caught another 100% Blaziken from raid, what are its next best movesets if I don’t want to use an Elite Charge TM to get Blast Burn on it?

It has another exclusive move that you can get without Elite Charge TMs called Blaze Kick. Otherwise, there’s Overheat and Focus Blast.

So for PvE, Fire Spin and Blaze Kick are the next best moves after Fire Spin and Blast Burn?

Yes, marginally so if you wish for a Fire-type moveset. Counter delivers more damage than Fire Spin, but reduces your super effectiveness spread to Steel-types only.

Thanks, Blaziken is better being a fire type than a fighting type under the current meta